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245011 Aldrich

Triruthenium dodecacarbonyl

99%

Synonym: Ruthenium carbonyl, tri-Ruthenium dodecacarbonyl

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Description

Application

Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.

Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,ß-unsaturated ketones providing good yields of α-pyrones.

General description

Atomic number of base material: 44 Ruthenium

Packaging

1, 5, 50 g in glass bottle

Other Notes

A Practical Procedure for Reduction of Primary, Secondary and Tertiary Amides to Amines

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Screeing simplified
Protocols & Articles

Articles

High Purity Metalorganic Precursors for CPV Device Fabrication

Thin film photovoltaic devices have become increasingly important in efficiently harnessing solar energy to meet consumer demand. Conventional crystalline silicon solar cells have demonstrated remark...
Ravi Kanjolia
Material Matters Volume 5 Article 4
Keywords: Absorption, Chemical vapor deposition, Degradations, Deposition, Mass spectrometry, Nuclear magnetic resonance spectroscopy, Purification, Semiconductor, Solar cells, Spectroscopy, Tissue microarrays, Vaporization

Michael Krische Group – Products available at Aldrich from the Krische Laboratory

From our library of Articles, Sigma-Aldrich presents Michael Krische Group – Products available at Aldrich from the Krische Laboratory
Keywords: Addition reactions, Asymmetric synthesis, C-C bond formation, Catalysis, Chromatography, Flash chromatography, Hydrogenations, Infrared spectroscopy, Ligands, Oxidations, Precipitation

Peer-Reviewed Papers
15

References

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