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247049 Aldrich

Tributylphosphine

mixture of isomers, 97%

Synonym: P(n-Bu)3, TBP, Tris(trimethylsilyl)phosphane

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
vapor density   9 (vs air)
InChI Key   TUQOTMZNTHZOKS-UHFFFAOYSA-N
assay   97%
autoignition temp.   392 °F
impurities   <1% TBP oxide
  5% TBP isomers
refractive index   n20/D 1.462(lit.)
bp   150 °C/50 mmHg(lit.)
density   0.81 g/mL at 25 °C(lit.)
ligand for   Acetylations
  Addition Reactions
  Stille Coupling

Description

Application

1,4-addition catalyst; used with disulfides for the thioetherification of alcohols; acylation catalyst; used to prepare active esters.

Used with platinum (II) or (IV) in an intermolecular hydroamination of unactivated alkenes.

Packaging

100, 500 g in Sure/Seal™

Price and Availability


Laboratory Gloves
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 3254 4.2 / PGI
WGK Germany 
3
RTECS 
SZ3270000
Flash Point(F) 
98.6 °F
Flash Point(C) 
37 °C
Protocols & Articles

Articles

Solvothermal Synthesis of Nanoparticles

Solvothermal synthesis is a method for preparing a variety of materials such as metals, semiconductors, ceramics, and polymers. The process involves the use of a solvent under moderate to high pressu...
Prof. Bonnie Gersten
Chemfiles Volume 5 Article 13
Keywords: Absorption, Applications, Ceramics, Reductions, Semiconductor, Spectra, Type

Peer-Reviewed Papers
15

References

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