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247685 Sigma-Aldrich

2-Fluoro-6-nitrotoluene

98%

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Properties

Related Categories Aryl Fluorinated Building Blocks, Building Blocks, C7, Chemical Synthesis, Fluorinated Building Blocks,
InChI Key   GXPIVRKDWZKIKZ-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.523 (lit.)
bp   97 °C/11 mmHg(lit.)
mp   6.5-7 °C (lit.)
density   1.27 g/mL at 25 °C (lit.)

Description

General description

2-Fluoro-6-nitrotoluene undergoes reduction in the presence of stannous chloride, followed by benzoylation to yield N-(3-fluoro-o-tolyl)benzamide. 2-Fluoro-6-nitrotoluene undergoes reaction with concentrated nitric acid at 100°C to yield 2-fluoro-6-nitrobenzoic acid.

Application

2-Fluoro-6-nitrotoluene has been used in the preparation of 4-fluoroindole via Leimgruber-Batcho procedure.

Packaging

10 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
WGK Germany 
3
Flash Point(F) 
192.2 °F
Flash Point(C) 
89 °C

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Protocols & Articles
Peer-Reviewed Papers
15

References

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