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248940 Sigma-Aldrich

(S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

97%

Synonym: (S)-(+)-1,1′-Binaphthalene-2,2′-diyl hydrogen phosphate, (S)-4-Hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

  • CAS Number 35193-64-7

  • Empirical Formula (Hill Notation) C20H13O4P

  • Molecular Weight 348.29

  •  Beilstein/REAXYS Number 4787775

  •  MDL number MFCD00010045

  •  PubChem Substance ID 24854963

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Phosphoric Acids, Chiral Resolution Reagents,
InChI Key   JEHUZVBIUCAMRZ-UHFFFAOYSA-N
assay   97%
optical activity   [α]22/D +595°, c = 1.35 in methanol

Description

Packaging

1, 5 g in glass bottle

Application

Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

HPLC Analysis of 1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate Enantiomers on Astec® (R,R) P-CAP™

From our library of Articles, Sigma-Aldrich presents HPLC Analysis of 1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate Enantiomers on Astec® (R,R) P-CAP™
Keywords: Chromatography, High performance liquid chromatography

Peer-Reviewed Papers
15

References

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