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  • 249262 - (−)-Corey lactone, 4-phenylbenzoate alcohol

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249262 Sigma-Aldrich

(−)-Corey lactone, 4-phenylbenzoate alcohol

99%

Synonym: (3aα,4α,5β,6aα)-(−)-Hexahydro-4-(hydroxymethyl)-2-oxo-2H-cyclopenta[b]furan-5-yl 1,1′-biphenyl-4-carboxylate, (3aR,4S,5R,6aS)-Hexahydro-4-hydroxymethyl-5-(4-phenylbenzoyloxy)cyclopenta[b]furan-2-one

  • CAS Number 31752-99-5

  • Empirical Formula (Hill Notation) C21H20O5

  • Molecular Weight 352.38

  •  Beilstein/REAXYS Number 1294692

  •  MDL number MFCD00078077

  •  PubChem Substance ID 24854983

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Lactones, Organic Building Blocks More...
Quality Level   100
assay   99%
optical activity   [α]20/D −87°, c = 1 in chloroform
mp   131-132 °C (lit.)
storage temp.   2-8°C
SMILES string   OC[C@H]1[C@@H](C[C@@H]2OC(=O)C[C@H]12)OC(=O)c3ccc(cc3)-c4ccccc4
InChI   1S/C21H20O5/c22-12-17-16-10-20(23)25-18(16)11-19(17)26-21(24)15-8-6-14(7-9-15)13-4-2-1-3-5-13/h1-9,16-19,22H,10-12H2/t16-,17-,18+,19-/m1/s1
InChI key   SZJVIFMPKWMGSX-AKHDSKFASA-N

Description

Application

Key intermediate in the synthesis of prostaglandins. Versatile building block for prostaglandins. Building block for a potent and selective antiglaucoma agent analog of PGF

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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