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252786 Sigma-Aldrich

2-Iodoanisole

98%

Synonym: 2-Iodophenyl methyl ether, 2-Methoxyiodobenzene

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Properties

Related Categories Building Blocks, C2 to C7, Chemical Synthesis, Ethers, Organic Building Blocks,
Quality Level   200
assay   98%
refractive index   n20/D 1.622 (lit.)
bp   125-126 °C/19 mmHg (lit.)
solubility   alcohol: miscible(lit.)
  chloroform: miscible(lit.)
  diethyl ether: miscible(lit.)
  water: insoluble(lit.)
density   1.799 g/mL at 25 °C (lit.)
SMILES string   COc1ccccc1I
InChI   1S/C7H7IO/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3
InChI key   DVQWNQBEUKXONL-UHFFFAOYSA-N

Description

General description

2-Iodoanisole participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.

Application

2-Iodoanisole has been used in palladium/copper-catalyzed synthesis of o-(1-alkynyl)anisoles.

Packaging

25, 100 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
235.4 °F - closed cup
Flash Point(C) 
113 °C - closed cup

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Protocols & Articles
Peer-Reviewed Papers
15

References

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