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252913 Sigma-Aldrich

5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride

≥95% (HPLC)

  • CAS Number 36965-71-6

  • Empirical Formula (Hill Notation) C44H8ClF20FeN4

  • Molecular Weight 1063.83

  •  MDL number MFCD00012151

  •  PubChem Substance ID 24855248

  •  NACRES NA.23

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron Catalysts, Materials Science, Organic and Printed Electronics,
Quality Level   100
assay   ≥95% (HPLC)
reaction suitability   reagent type: catalyst
core: iron
λmax   415 nm
  498 nm (2nd)
SMILES string   Fc1c(F)c(F)c(c(F)c1F)-c2c3ccc(n3)c(-c4c(F)c(F)c(F)c(F)c4F)c5ccc6c(-c7c(F)c(F)c(F)c(F)c7F)c8ccc(n8)c(-c9c(F)c(F)c(F)c(F)c9F)c%10ccc2n%10[Fe](Cl)n56
InChI   1S/C44H8F20N4.ClH.Fe/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;;/h1-8H;1H;/q-2;;+3/p-1/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;;
InChI key   RVNJZXLLVARDGN-VTVSBRCESA-M

Description

Application

Catalyst for epoxidations with peroxides, oxidative decarbonylations, and aliphatic hydroxylations.

Packaging

100 mg in glass insert

Features and Benefits

Catalyst for epoxidations with peroxides, oxidative decarbonylations, and aliphatic hydroxylations.

Preferred catalyst in catalytic oxygenation reactions.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Protocols & Articles

Articles

Novel Graphene‑Based Nanostructures Production, Functionalization, and Engineering

Manuela Melucci,1 Simone Ligi,2 Vincenzo Palermo3* 1ISOF – Consiglio Nazionale delle Ricerche (CNR), Italy 2GNext sas, Italy 3ISOF – Consiglio Nazionale delle Ricerche (CNR), Italy *Email: vincenzo.p...
Keywords: Absorption, Asymmetric synthesis, Catalysis, Deposition, Electronics, Evaporation, Nucleic acid annealing, Oxidations, Reductions, Semiconductor, Silylations, Solvents, Sonication

Peer-Reviewed Papers
15

References

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