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  • 257532 - 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine iron(III) chloride

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257532 Sigma-Aldrich

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine iron(III) chloride

  • CAS Number 28755-93-3

  • Empirical Formula (Hill Notation) C36H44ClFeN4

  • Molecular Weight 624.06

  •  MDL number MFCD00011614

  •  PubChem Substance ID 24855420

  •  NACRES NA.23

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Properties

Related Categories Materials Science, Organic and Printed Electronics, Photonic and Optical Materials, Phthalocyanine and Porphyrin Dyes, Porphyrines More...
Quality Level   100
λmax   382 nm
SMILES string   CCc1c(CC)c2cc3c(CC)c(CC)c4cc5nc(cc6c(CC)c(CC)c(cc1n2)n6[Fe](Cl)n34)c(CC)c5CC
InChI   1S/C36H44N4.ClH.Fe/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;;/h17-20H,9-16H2,1-8H3;1H;/q-2;;+3/p-1/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;;
InChI key   NWWCYXFDLUMYRQ-YAJYDHHFSA-M

Description

General description

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine metalates with iron chloride to form 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine iron chloride (FeOEP). It may be used to form Langmuir Blodgett (LB) thin films. Iron–porphyrin could be present naturally in biofilms.

Application

An iron–porphyrin adlayer adsorbed on the Au(111) substrate was used to study the electrocatalytic reduction of O2 in HClO4.

Packaging

100 mg in glass insert

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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