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258911 Sigma-Aldrich

Ethyl benzoylformate

95%

Synonym: Ethyl phenylglyoxylate

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Properties

Related Categories Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Esters,
assay   95%
refractive index   n20/D 1.516 (lit.)
bp   138-139 °C/18 mmHg (lit.)
density   1.122 g/mL at 25 °C (lit.)
SMILES string   CCOC(=O)C(=O)c1ccccc1
InChI   1S/C10H10O3/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7H,2H2,1H3
InChI key   QKLCQKPAECHXCQ-UHFFFAOYSA-N

Description

General description

Enantioselective hydrogenation of ethyl benzoylformate on Pt/Al2O3 modified with dihydrocinchonidine has been studied.

Application

Ethyl benzoylformate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
>235.4 °F
Flash Point(C) 
>113 °C

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Protocols & Articles
Peer-Reviewed Papers
15

References

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