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259039 Sigma-Aldrich

Chloro(1,5-hexadiene)rhodium(I),dimer

98%

Synonym: Di-μ-chlorobis[(1,2,5,6-η)-1,5-hexadiene]dirhodium

  • CAS Number 32965-49-4

  • Linear Formula [(H2C=CHCH2CH2CH=CH2)RhCl]2

  • Molecular Weight 434.96

  •  MDL number MFCD00064595

  •  PubChem Substance ID 24855679

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts More...
assay   98%
mp   118-120 °C (lit.)
reaction suitability   reagent type: catalyst
SMILES string   Cl[Rh].Cl[Rh].C=CCCC=C.C=CCCC=C
InChI   1S/2C6H10.2ClH.2Rh/c2*1-3-5-6-4-2;;;;/h2*3-4H,1-2,5-6H2;2*1H;;/q;;;;2*+1/p-2
InChI key   HXNWPVBAYNUADR-UHFFFAOYSA-L

Description

Application

Catalyst for:
• Hydrogenation
• Enantioselective hydrosilylation

Useful catalyst for the reduction of arenes and heterocyclic compounds using CTAB or THS as phase-transfer catalyst.

Packaging

250 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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