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261971 Sigma-Aldrich

Tricyclohexylphosphine

Synonym: P(Cy)3, PCy3

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Properties

Related Categories Basic Phosphine Ligands, Buchwald Ligands and Complexes, Buchwald and Related Ligands, Catalysis, Catalysis and Inorganic Chemistry,
InChI Key   WLPUWLXVBWGYMZ-UHFFFAOYSA-N
mp   81-83 °C (lit.)
reaction suitability   reagent type: ligand
reaction type: Heck Reaction
  reagent type: ligand
reaction type: Hiyama Coupling
  reagent type: ligand
reaction type: Sonogashira Coupling
  reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

Description

Application

Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides. Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides.

This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.

Packaging

1, 5, 25, 250 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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