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273112 Sigma-Aldrich

(1R,E)-(+)-Camphorquinone 3-oxime

99%

Synonym: (1R,E)-(+)-2,3-Bornanedione 3-oxime, anti-(1R)-(+)-Camphorquinone 3-oxime

  • CAS Number 31571-14-9

  • Empirical Formula (Hill Notation) C10H15NO2

  • Molecular Weight 181.23

  •  Beilstein/REAXYS Number 3200377

  •  MDL number MFCD00074848

  •  PubChem Substance ID 24856531

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Oximes More...
Quality Level   100
assay   99%
optical activity   [α]25/D +200°, c = 1 in ethanol
mp   153-156 °C (lit.)
SMILES string   [H][C@@]12CC[C@@](C)(C(=O)\C1=N/O)C2(C)C
InChI   1S/C10H15NO2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11-13/h6,13H,4-5H2,1-3H3/b11-7-/t6-,10+/m1/s1
InChI key   YRNPDSREMSMKIY-HAKKTOSXSA-N

Description

Application

(1R,E)-(+)-Camphorquinone 3-oxime can be used to prepare chiral camphor-oxazoline auxiliary, which is used to blend diastereoselectivity and isomer separability for the efficient synthesis of bicuculline, egenine, corlumine, and corytensine.

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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