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275700 Sigma-Aldrich

2,3-Dichlorohexafluoro-2-butene, mixture of cis and trans

99%

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Properties

Related Categories Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks More...
vapor density   8 (vs air)
vapor pressure   4.42 psi ( 20 °C)
assay   99%
refractive index   n20/D 1.3458 (lit.)
bp   66-68 °C (lit.)
density   1.605 g/mL at 25 °C (lit.)
SMILES string   FC(F)(F)C(\Cl)=C(/Cl)C(F)(F)F
InChI   1S/C4Cl2F6/c5-1(3(7,8)9)2(6)4(10,11)12/b2-1+
InChI key   XDIDQEGAKCWQQP-OWOJBTEDSA-N

Description

General description

The pure cis- and trans-isomers of 2,3-dichlorohexafluoro-2-butene were separated when 2,3-dichlorohexafluoro-2-butene (mixture of cis and trans) reacted with dry diglyme and sodium borohydride and was hydolyzed. The isomers were purified by preparative vapor phase chromatography technique.

Packaging

10 g in ampule

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3389 8(6.1) / PGI
WGK Germany 
3
RTECS 
EM4910000

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Protocols & Articles
Peer-Reviewed Papers
15

References

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