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275794 Sigma-Aldrich

Tris(trimethylsilyl) phosphate

≥98%

Synonym: Phosphoric acid tris(trimethylsilyl ester)

  • CAS Number 10497-05-9

  • Linear Formula [(CH3)3SiO]3P(O)

  • Molecular Weight 314.54

  •  Beilstein/REAXYS Number 1794624

  •  EC Number 234-028-1

  •  MDL number MFCD00008267

  •  PubChem Substance ID 24856672

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds More...
Quality Level   200
assay   ≥98%
refractive index   n20/D 1.409 (lit.)
bp   228-229 °C/720 mmHg (lit.)
mp   3-4 °C (lit.)
density   0.945 g/mL at 25 °C (lit.)
SMILES string   C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C
InChI   1S/C9H27O4PSi3/c1-15(2,3)11-14(10,12-16(4,5)6)13-17(7,8)9/h1-9H3
InChI key   QJMMCGKXBZVAEI-UHFFFAOYSA-N

Description

General description

Tris(trimethylsilyl) phosphate has been investigated as a novel film-forming additive for LiNi0.5Co0.2Mn0.3O2 cycling at high cut-off potential in LiPF6-based electrolyte. Tris(trimethylsilyl) phosphate [Tris(trimethylsilyl) ester of phosphoric acid] undergoes dealkylsilylation reaction with alumazene to yield heteroadamantane molecule.

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
UN 1993BF 3 / PGII
WGK Germany 
WGK 2
RTECS 
TC9700000
Flash Point(F) 
55.4 °F - closed cup
Flash Point(C) 
13 °C - closed cup

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Protocols & Articles
Peer-Reviewed Papers
15

References

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