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275867 Sigma-Aldrich

5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphine cobalt(II)

  • CAS Number 28903-71-1

  • Empirical Formula (Hill Notation) C48H36CoN4O4

  • Molecular Weight 791.76

  •  MDL number MFCD00010724

  •  PubChem Substance ID 24856676

  •  NACRES NA.23

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt Catalysts, Materials Science, Organic and Printed Electronics,
Quality Level   200
reaction suitability   reagent type: catalyst
core: cobalt
λmax   417 nm
  530 nm (2nd)
SMILES string   COc1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(OC)cc4)c5ccc6c(-c7ccc(OC)cc7)c8ccc(n8)c(-c9ccc(OC)cc9)c%10ccc2n%10[Co]n56
InChI   1S/C48H36N4O4.Co/c1-53-33-13-5-29(6-14-33)45-37-21-23-39(49-37)46(30-7-15-34(54-2)16-8-30)41-25-27-43(51-41)48(32-11-19-36(56-4)20-12-32)44-28-26-42(52-44)47(40-24-22-38(45)50-40)31-9-17-35(55-3)18-10-31;/h5-28H,1-4H3;/q-2;+2/b45-37-,45-38-,46-39-,46-41-,47-40-,47-42-,48-43-,48-44-;
InChI key   QBCIMRXPMLWVML-NHZJRHMYSA-N

Description

Packaging

1, 10 g in glass bottle

Application

Starting material in the synthesis of cobalt nitrosyl porphyrins for use in the study of the binding and activation of nitric oxide.

Features and Benefits

Acts as a versatile catalyst during the oxidation of a wide range of organic substrates with dioxygen in the presence of 2-methylpropanal under ambient conditions.

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Novel Graphene‑Based Nanostructures Production, Functionalization, and Engineering

Manuela Melucci,1 Simone Ligi,2 Vincenzo Palermo3* 1ISOF – Consiglio Nazionale delle Ricerche (CNR), Italy 2GNext sas, Italy 3ISOF – Consiglio Nazionale delle Ricerche (CNR), Italy *Email: vincenzo.p...
Keywords: Absorption, Asymmetric synthesis, Catalysis, Deposition, Electronics, Evaporation, Nucleic acid annealing, Oxidations, Reductions, Semiconductor, Silylations, Solvents, Sonication

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