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278033 Sigma-Aldrich

Diethyl isopropylidenemalonate

97%

  • CAS Number 6802-75-1

  • Linear Formula (CH3)2C=C(COOC2H5)2

  • Molecular Weight 200.23

  •  Beilstein/REAXYS Number 1776122

  •  EC Number 229-876-4

  •  MDL number MFCD00009147

  •  PubChem Substance ID 24856502

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Properties

Related Categories Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Esters,
InChI Key   WEISAZNMMVPNTH-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.451 (lit.)
bp   175-178 °C/120 mmHg(lit.)
density   1.021 g/mL at 25 °C (lit.)

Description

General description

Reduction of diethyl isopropylidenemalonate with sodium borohydride has been reported.

Application

Diethyl isopropylidenemalonate has been used in the synthesis of retinoids having functional groups at the side-chain terminus.

Packaging

25 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
176 °F
Flash Point(C) 
80 °C

Documents

Certificate of Analysis

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Protocols & Articles
Peer-Reviewed Papers
15

References

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