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281042 Sigma-Aldrich

Tetradecafluorohexane

99%

Synonym: Perfluorohexane

  • CAS Number 355-42-0

  • Linear Formula CF3(CF2)4CF3

  • Molecular Weight 338.04

  •  Beilstein/REAXYS Number 1802113

  •  EC Number 206-585-0

  •  MDL number MFCD00000437

  •  PubChem Substance ID 24856965

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Properties

Related Categories Alkyl, Building Blocks, Chemical Synthesis, F-Tagged, Fluorinated Building Blocks,
InChI Key   ZJIJAJXFLBMLCK-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.252 (lit.)
bp   58-60 °C(lit.)
mp   -74 °C (lit.)
density   1.669 g/mL at 25 °C (lit.)

Description

General description

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.

Application

Tetradecafluorohexane has been used:
• as a fluorocarbon organic solvent in the preparation of temperature-induced phase-separation solution
• to investigate boiling heat transfer mechanisms
• as a photosensitizer in fluorous biphasic singlet oxygenation
• as a novel reaction medium for photooxidation reactions

Packaging

25 mL in ampule

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
2
RTECS 
MO4310000

Documents

Certificate of Analysis

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Meet Synthia - Retrosynthesis Sofware
Protocols & Articles
Peer-Reviewed Papers
15

References

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