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281239 Sigma-Aldrich

Diallyl carbonate

99%

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Properties

Related Categories Allyl Monomers, Materials Science, Monomers, Polymer Science
InChI Key   JKJWYKGYGWOAHT-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.428 (lit.)
bp   95-97 °C/60 mmHg (lit.)
density   0.991 g/mL at 25 °C (lit.)
storage temp.   2-8°C

Description

General description

Diallyl carbonate is an acrylating agent. Allyl carbonates are widely employed in Tsuji-Trost allylation, generating carbanion, boronate, phosphide, amide and alkoxide, nucleophiles in situ and improving reaction rates over allyl acetate. Allyl carbonates are also of considerable interest for the intramolecular decarboxylative assymetric couplings.

Application

Transesterification of diallyl carbonate with glycerol in the presence of a catalyst (Pd/PPh3), generates glycerol carbonate.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 3272 3 / PGIII
WGK Germany 
3
Flash Point(F) 
138.2 °F
Flash Point(C) 
59 °C
Protocols & Articles
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08168 Timestrip Plus 8 °C

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