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282146 Sigma-Aldrich

(1R)-(−)-10-Camphorsulfonic acid

98%

Synonym: (−)-Camphor-10-sulfonic acid, (1R)-(−)-Camphor-10-sulfonic acid, (1R)-Camphor-10-sulfonic acid

  • CAS Number 35963-20-3

  • Empirical Formula (Hill Notation) C10H16O4S

  • Molecular Weight 232.30

  •  Beilstein/REAXYS Number 2809676

  •  EC Number 252-817-9

  •  MDL number MFCD00064158

  •  PubChem Substance ID 24857020

  •  NACRES NA.22

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Properties

Related Categories Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks,
Quality Level   100
assay   98%
optical activity   [α]20/D −21°, c = 2 in H2O
mp   198 °C (dec.) (lit.)
SMILES string   [H][C@]12CC[C@](CS(O)(=O)=O)(C(=O)C1)C2(C)C
InChI   1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m0/s1
InChI key   MIOPJNTWMNEORI-XVKPBYJWSA-N

Description

General description

(1R)-(−)-10-Camphorsulfonic acid is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed for the resolution of bases.

Application

(1R)-(−)-10-Camphorsulfonic acid may be used as a chiral building block for the synthesis of pentavalent organo-bismuth derivatives by enantioselective C-arylation. It may be used as a chiral monomer in the enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films.

Packaging

25, 100 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3261 8 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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