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282855 Sigma-Aldrich

3-Methyl-2,4-pentanedione, mixture of tautomers

technical grade, 85%

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Properties

Related Categories Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones,
Quality Level   100
grade   technical grade
assay   85%
refractive index   n20/D 1.442 (lit.)
bp   172-174 °C (lit.)
density   0.981 g/mL at 25 °C (lit.)
SMILES string   CC(C(C)=O)C(C)=O
InChI   1S/C6H10O2/c1-4(5(2)7)6(3)8/h4H,1-3H3
InChI key   GSOHKPVFCOWKPU-UHFFFAOYSA-N

Description

General description

Peroxynitrite promoted aerobic oxidation of 3-methyl-2,4-pentanedione has been reported. The kinetics of the reaction of OH radicals with 3-methyl-2,4-pentanedione has been investigated in the gas-phase using a pulsed laser photolysis-laser induced fluorescence technique. 3-methyl-2,4-pentanedione participates in asymmetric substitution of 1,3-diphenyl-2-propenyl acetate catalyzed by amphiphilic resin-supported monodentate phosphine ligands.

Packaging

25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
UN1224 - class 3 - PG 3 - Ketones, liquid, n.o.s., HI: all
WGK Germany 
WGK 3
Flash Point(F) 
134.6 °F - closed cup
Flash Point(C) 
57 °C - closed cup

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Protocols & Articles
Peer-Reviewed Papers
15

References

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