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288403 Sigma-Aldrich

trans-Dichlorobis(triphenylphosphine)platinum(II)

Synonym: trans-Bis(triphenylphosphine)platinum dichloride

  • CAS Number 14056-88-3

  • Linear Formula [(C6H5)3P]2PtCl2

  • Molecular Weight 790.56

  •  MDL number MFCD00010825

  •  PubChem Substance ID 24857337

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Platinum Catalysts More...
reaction suitability   core: platinum
  reagent type: catalyst
SMILES string   Cl[Pt]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI   1S/2C18H15P.2ClH.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChI key   XAFJSPPHVXDRIE-UHFFFAOYSA-L

Description

Application

Catalyst for:
• Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groups
• Alkynylation and hydrogenation reactions
• Hetero-Diels-Alder/ring-opening reactions
• Insertion of carbenes into O-H bonds of alcohols
• Cyclopropanation of olefins
• Hydroformylation reactions

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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