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291390 Sigma-Aldrich

p-Tolyl acetate

99%

Synonym: p-Cresyl acetate

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Properties

Related Categories Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters,
InChI Key   CDJJKTLOZJAGIZ-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.501 (lit.)
bp   210-211 °C (lit.)
density   1.047 g/mL at 25 °C (lit.)

Description

General description

The Fries rearrangement of p-tolyl acetate has been investigated using the H-form of various zeolites as catalysts. Mechanism of photo-Fries rearrangement of p-tolyl acetate has been studied.

Application

p-Tolyl acetate has been used in the total synthesis of (−)-incrustoporin.

Packaging

5, 250 mL in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NA 1993 / PGIII
WGK Germany 
2
RTECS 
AJ7570000
Flash Point(F) 
194 °F
Flash Point(C) 
90 °C
Protocols & Articles

Articles

Fries Rearrangement

The Fries rearrangement reaction is an organic name reaction which involves the conversion of phenolic esters into hydroxyaryl ketones on heating in the presence of a catalyst. Suitable catalysts for...
Keywords: Acylations, Addition reactions, Agrochemicals, Antivirals, Catalysis, Fries Rearrangement, Michael Addition, Pharmaceutical, Rearrangements, Vitamins

Peer-Reviewed Papers
15

References

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