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293474 Sigma-Aldrich

4-Bromo-2-fluoroanisole

97%

Synonym: 4-Bromo-2-fluoro-1-methoxybenzene

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Properties

Related Categories Aryl Fluorinated Building Blocks, Building Blocks, C2 to C7, C7, Chemical Synthesis,
Quality Level   100
assay   97%
refractive index   n20/D 1.545 (lit.)
bp   84 °C/7 mmHg (lit.)
density   1.59 g/mL at 25 °C (lit.)
SMILES string   COc1ccc(Br)cc1F
InChI   1S/C7H6BrFO/c1-10-7-3-2-5(8)4-6(7)9/h2-4H,1H3
InChI key   DWNXGZBXFDNKOR-UHFFFAOYSA-N

Description

General description

The IR and FT-IR spectra of 4-bromo-2-fluoroanisole have been investigated.

Application

4-Bromo-2-fluoroanisole has been used in the synthesis of:
• 1,4-bis[(3′-fluoro-4′-n alkoxyphenyl)ethynyl]benzenes with n=1-12
• 7-fluoro-6-methoxy-1-methyl-2-naphthaldehyde
• 5,7-difluoro-6-methoxy-1-methyl-2-naphthaldehyde
• liquid crystals with terminal difluoromethoxy group and backbone of phenylbicyclohexane

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
208.4 °F - closed cup
Flash Point(C) 
98 °C - closed cup

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Protocols & Articles
Peer-Reviewed Papers
15

References

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