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294640 Sigma-Aldrich

(S)-4-Benzyl-2-oxazolidinone

99%

  • CAS Number 90719-32-7

  • Empirical Formula (Hill Notation) C10H11NO2

  • Molecular Weight 177.20

  •  Beilstein/REAXYS Number 3649667

  •  MDL number MFCD00064496

  •  PubChem Substance ID 24857725

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Auxiliaries, Oxazolidinone Derivatives
Quality Level   200
assay   99%
optical activity   [α]20/D −63°, c = 1 in chloroform
optical purity   ee: 99% (HPLC)
mp   86-88 °C (lit.)
SMILES string   O=C1N[C@H](CO1)Cc2ccccc2
InChI   1S/C10H11NO2/c12-10-11-9(7-13-10)6-8-4-2-1-3-5-8/h1-5,9H,6-7H2,(H,11,12)/t9-/m0/s1
InChI key   OJOFMLDBXPDXLQ-VIFPVBQESA-N

Description

Packaging

5, 25 g in poly bottle

Application

Chiral auxiliary for asymmetric alkylation.

Chiral auxiliary used recently in a synthesis of (S)-equol. Preparation and functionalization of chiral, stabilized ylides.

Used for asymmetric synthesis of (3R)- and (3S)-piperazic acid.

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

HPLC Analysis of 4-Benzyl-2-oxazolidinone Enantiomers on Astec® CHIROBIOTIC® TAG

From our library of Articles, Sigma-Aldrich presents HPLC Analysis of 4-Benzyl-2-oxazolidinone Enantiomers on Astec® CHIROBIOTIC® TAG
Keywords: Chromatography, High performance liquid chromatography

Peer-Reviewed Papers
15

References

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