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29510 Aldrich

(R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) Green Alternative

≥97%, optical purity ee: ≥99%

Synonym: (R)-(+)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl, (R)-(+)-MeO-BIPHEP, SL-A101-1

  • CAS Number 133545-16-1

  • Empirical Formula (Hill Notation) C38H32O2P2

  • Molecular Weight 582.61

  •  Beilstein Registry Number 4790083

  •  MDL number MFCD03095430

  •  PubChem Substance ID 24857757

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, MeOBIPHEP Ligands, Privileged Ligands and Complexes,
InChI Key   KRJVQCZJJSUHHO-UHFFFAOYSA-N
assay   ≥97%
optical purity   ee: ≥99%
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.

Description

General description

sold in collaboration with Solvias AG

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Application

Atropisomeric MeOBIPHEP ligands

• Hydrogenation of α- and β-functionalized ketones
• Hydrogenation of heteroarenes
• C–C coupling reactions

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Related Content

Solvias Chiral Phosphine Ligands - Toolkit for Asymmetric Catalysis

Sigma-Aldrich, in collaboration with Solvias, is proud to present the Chiral Ligands Kit – the ultimate toolkit for asymmetric catalysis!
Keywords: Asymmetric catalysis, Asymmetric synthesis, Catalysis, Individual protein Immunoprecipitation, Ligands

Peer-Reviewed Papers
15

References

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