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297054 Sigma-Aldrich

(Trimethylsilyl)methyllithium solution

1.0 M in pentane

  • CAS Number 1822-00-0

  • Linear Formula (CH3)3SiCH2Li

  • Molecular Weight 94.16

  •  Beilstein/REAXYS Number 4123225

  •  MDL number MFCD00010747

  •  PubChem Substance ID 24857896

  •  NACRES NA.22

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Properties

Related Categories 25mL Sure/Seal Reagents, Alkyl, Chemical Synthesis, Organolithium, Organometallic Reagents More...
concentration   1.0 M in pentane
bp   35-36 °C
density   0.65 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   [Li]C[Si](C)(C)C
InChI   1S/C4H11Si.Li/c1-5(2,3)4;/h1H2,2-4H3;
InChI key   RJPBNMJOQNIBQW-UHFFFAOYSA-N

Description

Application

Initiates polymerization and copolymerization of cyclosiloxanes. Alkylates metal complexes.

Packaging

4×25, 50, 600 mL in Sure/Seal™

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
Target organs 
Central nervous system
Supplemental Hazard Statements 
EUH014
RIDADR 
UN 3399A 4.3(3) / PGI
WGK Germany 
WGK 3
Flash Point(F) 
-56.2 °F - closed cup
Flash Point(C) 
-49 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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