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297801 Sigma-Aldrich

Methyl 2-amino-3,5-dibromobenzoate

98%

Synonym: Methyl 3,5-dibromoanthranilate

  • CAS Number 606-00-8

  • Linear Formula Br2C6H2-2-(NH2)CO2CH3

  • Molecular Weight 308.95

  •  MDL number MFCD00010873

  •  PubChem Substance ID 24857930

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Properties

Related Categories Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters,
assay   98%
mp   89-91 °C (lit.)
SMILES string   COC(=O)c1cc(Br)cc(Br)c1N
InChI   1S/C8H7Br2NO2/c1-13-8(12)5-2-4(9)3-6(10)7(5)11/h2-3H,11H2,1H3
InChI key   NGXVMFCGYYHEGC-UHFFFAOYSA-N

Description

General description

Methyl 2-amino-3,5-dibromobenzoate participates in cobalt(II) Schiff′s base complex catalyzed oxidation of primary and secondary alcohols to aldehydes and ketones respectively. It also participates in allylic and benzylic oxidation of various cyclic alkenes and benzylic compounds respectively.

Application

Methyl 2-amino-3,5-dibromobenzoate was used in the preparation of ethyl 1-(p-methoxyphenyl)-2-oxocyclopentanecarboxylate via reaction with chloroform containing pyridine.

Packaging

25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Meet Synthia - Retrosynthesis Sofware
Protocols & Articles
Peer-Reviewed Papers
15

References

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