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  • 297917 - Methyl 2,2-dichloro-2-methoxyacetate

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297917 Sigma-Aldrich

Methyl 2,2-dichloro-2-methoxyacetate

97%

  • CAS Number 17640-25-4

  • Linear Formula Cl2C(OCH3)CO2CH3

  • Molecular Weight 172.99

  •  MDL number MFCD00012202

  •  PubChem Substance ID 24857947

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters,
assay   97%
refractive index   n20/D 1.45 (lit.)
bp   179-181 °C (lit.)
density   1.36 g/mL at 25 °C (lit.)
storage temp.   room temp
SMILES string   COC(=O)C(Cl)(Cl)OC
InChI   1S/C4H6Cl2O3/c1-8-3(7)4(5,6)9-2/h1-2H3
InChI key   FWIGIASHGJFYOL-UHFFFAOYSA-N

Description

Application

Methyl 2,2-dichloro-2-methoxyacetate was used in the preparation of methyl (Z)-α-methoxyacrylates via stereospecific two-carbon homologation of aldehydes under Barbier conditions.

Packaging

25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
UN 3265 8 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
195.8 °F - closed cup
Flash Point(C) 
91 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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