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298174 Sigma-Aldrich

Sodium tetrachloroaurate(III) dihydrate

99%

Synonym: Sodium gold chloride

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Gold Catalysts, Gold Complexes,
Quality Level   100
assay   99%
form   solid
SMILES string   O.O.[Na+].Cl[Au-](Cl)(Cl)Cl
InChI   1S/Au.4ClH.Na.2H2O/h;4*1H;;2*1H2/q+3;;;;;+1;;/p-4
InChI key   OEERDTKOVZFOHF-UHFFFAOYSA-J

Description

Application

A water/alcohol soluble Au(I) complex formed from NaAuCl4 has potential for application in chemotherapeutics.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Gold Catalysis - Aldrich ChemFiles 2007, 7.5, 10.

Gold catalysis is playing an increasing role in organic synthesis for the facile construction of complex architectures not readily accessed by standard methods. Gold catalysts mediate unique C–C, C–O...
Aldrich ChemFiles 2007, 7.5, 10.
Keywords: Catalysis, Chemfiles, Enyne rearrangements, Heterocycle formation, Isomerizations, Methods, Organic synthesis, Rearrangements

Hydroamination

The hydroamination reaction allows the introduction of an amine across the triple bond of an alkyne. This atom economic reaction is usually performed at room temperature.1 The challenge resides in th...
William Sommer
Aldrich ChemFiles 2009, 9.5, 3.
Keywords: Catalysis, Chemfiles, Hydroaminations

Related Content

Gold Catalyst in Chemical Synthesis

Introduction Hashmi, Toste, Echavarren, and Haruta, among others, have fueled the advance of gold into the forefront of transition metal catalysis.1,2 Phosphine ligated gold(I) complexes have risen a...
Keywords: Asymmetric synthesis, Building blocks, Catalysis, Claisen rearrangement, Conia-Ene Reaction, Cyclizations, Cycloadditions, Cycloisomerizations, Cyclopropanations, Deprotonations, Ene reaction, Hydroaminations, Hydrogenations, Isomerizations, Ligands, Rautenstrauch rearrangements, Rearrangements, Reductions, Schmidt Reaction, Substitutions

Peer-Reviewed Papers
15

References

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