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298433 Sigma-Aldrich

Dichloroborane methyl sulfide complex

in excess methyl sulfide

Synonym: Boron dichloride methyl sulfide complex, Dichloro(dimethyl sulfide)(hydro)boron, Dichloro(dimethyl sulfide)borane, Dichloroborane dimethyl sulfide

  • CAS Number 63462-42-0

  • Linear Formula (CH3)2S·BHCl2

  • Molecular Weight 144.86

  •  MDL number MFCD00013209

  •  PubChem Substance ID 24857986

  •  NACRES NA.22

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
density   1.255 g/mL at 25 °C (lit.)
SMILES string   C[S+](C)[BH-](Cl)Cl
InChI   1S/C2H7BCl2S/c1-6(2)3(4)5/h3H,1-2H3
InChI key   UMDZKXAEAKAIPA-UHFFFAOYSA-N

Description

Application

Reactant for:
• Hydroboration reactions
• Pyrolysis reactions
• Addition reactions
• Preparation of unsymmetrical borafluorenes
• Cyclization reactions
• Dismutation followed by haloboration of azadiboriridine to give boron-nitrogen clusters
• Markovnikov hydroboration

Packaging

50 g in Sure/Seal™

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 2920 3(8) / PGII
WGK Germany 
3
Flash Point(F) 
75.2 °F
Flash Point(C) 
24 °C

Documents

Certificate of Analysis (COA)

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