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298441 Sigma-Aldrich

Chloroborane methyl sulfide complex

Synonym: Boron monochloride methyl sulfide complex, Chloro(dimethyl sulfide)dihydroboron, Monochloroborane-dimethyl sulfide, monoChloroborane methyl sulfide complex

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   CUKLQTNDSCOWTI-UHFFFAOYSA-N
density   1.059 g/mL at 25 °C (lit.)

Description

Application

Reactant for:
• Substitution reactions
• Boronation reactions
• Preparation of diborylamines
• Preparation of unsymmetrical borafluorenes via low-temperature carbon-hydrogen activation reactions
• Asymmetrical aldol reactions with a-chiral aldehydes
• Addition reaction with α-pinene

Reagent for hydroboration and synthesis of chlorodialkylboranes.

Packaging

50 g in Sure/Seal™

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 2920 3(8) / PGII
WGK Germany 
3
Flash Point(F) 
75.2 °F
Flash Point(C) 
24 °C

Documents

Certificate of Analysis

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Protocols & Articles
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