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302341 Sigma-Aldrich

Acetoxyacetic acid

99%

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Properties

Related Categories Building Blocks, C1 to C5, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis,
assay   99%
bp   141-142 °C/12 mmHg (lit.)
mp   67-69 °C (lit.)
SMILES string   CC(=O)OCC(O)=O
InChI   1S/C4H6O4/c1-3(5)8-2-4(6)7/h2H2,1H3,(H,6,7)
InChI key   MLXDUYUQINCFFV-UHFFFAOYSA-N

Description

General description

Acetoxyacetic acid is kinetically stable degradation product of oxidative degradation of 1,3-dialkylimidazolium ionic liquids in hydrogen peroxide/aceticacid aqueous medium assisted by ultrasonic chemical irradiation. It is an intermediate formed during reactions of manganic acetate in glacial acetic acid with benzene (100°C), chlorobenzene, or toluene.

Application

Acetoxyacetic acid was used in preparation of tert-butyl glycolate.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3261 8 / PGII
WGK Germany 
3

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Protocols & Articles
Peer-Reviewed Papers
15

References

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