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305294 Sigma-Aldrich

(Trimethylsilyl)methanol

98%

Synonym: (Hydroxymethyl)trimethylsilane

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Properties

Related Categories Alcohols, Building Blocks, C2 to C6, Chemical Synthesis, Organic Building Blocks,
assay   98%
refractive index   n20/D 1.419 (lit.)
bp   120-122 °C/754 mmHg (lit.)
density   0.826 g/mL at 25 °C (lit.)
storage temp.   2-8°C
SMILES string   C[Si](C)(C)CO
InChI   1S/C4H12OSi/c1-6(2,3)4-5/h5H,4H2,1-3H3
InChI key   ZQKNBDOVPOZPLY-UHFFFAOYSA-N

Description

Application

(Trimethylsilyl)methanol was employed as nucleophile to resolve the racemate obtained from enantioselective esterification of naproxen (2-(6-methoxy-2-naphthyl) propionic acid) by lipases. It was also used as a nucleophilic hydroxymethylation agent.

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 1987C 3 / PGIII
WGK Germany 
3
RTECS 
PC4100000
Flash Point(F) 
132.8 °F
Flash Point(C) 
56 °C

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Protocols & Articles
Peer-Reviewed Papers
15

References

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