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317632 Sigma-Aldrich

(Methylcyclopentadienyl)manganese(I) tricarbonyl

Synonym: (Methylcyclopentadienyl)tricarbonylmanganese, Ethyl MMT, MCMT, MMT, NSC 22316, Tricarbonyl(2-methylcyclopentadienyl)manganese

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Manganese Catalysts More...
vapor pressure   0.05 mmHg ( 20 °C)
vapor density   >1 (vs air)
reaction suitability   reagent type: catalyst
refractive index   n20/D 1.584 (lit.)
bp   232-233 °C (lit.)
mp   −1 °C (lit.)
density   1.38 g/mL at 25 °C (lit.)
SMILES string   [Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].C[C]1[CH][CH][CH][CH]1
InChI   1S/C6H7.3CO.Mn/c1-6-4-2-3-5-6;3*1-2;/h2-5H,1H3;;;;
InChI key   LYHJNAIHGFWRKM-UHFFFAOYSA-N

Description

General description

Methylcyclopentadienyl manganese tricarbonyl (MMT) is commonly used as an antiknock agent in gasoline.

Application

Methylcyclopentadienyl manganese tricarbony is used for doping of ZnSe nanocrystals

It is a reactant for:
• Aldol addition reactions
• Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units
• Molecular fragmentation using shaped femtosecond laser pulses
• Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE)

Packaging

1, 50 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Target organs 
Lungs
RIDADR 
UN 3281 6.1 / PGII
WGK Germany 
WGK 3
RTECS 
OP1450000
Flash Point(F) 
204.8 °F - closed cup
Flash Point(C) 
96 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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