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325090 Sigma-Aldrich

Methyl (R)-(+)-3-bromo-2-methylpropionate

97%

Synonym: (+)-Methyl (R)-β-bromoisobutyrate

  • CAS Number 110556-33-7

  • Linear Formula BrCH2CH(CH3)CO2CH3

  • Molecular Weight 181.03

  •  Beilstein/REAXYS Number 1720833

  •  MDL number MFCD00010639

  •  PubChem Substance ID 24859486

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Esters, Organic Building Blocks More...
InChI Key   FKWNAVCXZSQYTA-BYPYZUCNSA-N
assay   97%
optical activity   [α]20/D +16°, neat
optical purity   ee: 99% (GLC)
refractive index   n20/D 1.455 (lit.)
bp   85 °C/37 mmHg (lit.)
density   1.422 g/mL at 25 °C (lit.)

Description

Application

Methyl (R)-(+)-3-bromo-2-methylpropionate may be used as a reference compound to determine the enantioselectivity of the alkylation reaction of hydrophobic vitamin B12 derivatives.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
163.4 °F
Flash Point(C) 
73 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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