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325104 Sigma-Aldrich

3-Nitrophenylboronic acid

≥97%

Synonym: 3-Nitrobenzeneboronic acid, m-Nitrobenzeneboronic acid, m-Nitrophenylboronic acid, NSC 401539, NSC 59739

  • CAS Number 13331-27-6

  • Linear Formula O2NC6H4B(OH)2

  • Molecular Weight 166.93

  •  Beilstein/REAXYS Number 2938638

  •  MDL number MFCD00007193

  •  PubChem Substance ID 24859487

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids,
InChI Key   ZNRGSYUVFVNSAW-UHFFFAOYSA-N
assay   ≥97%
mp   284-285 °C (dec.) (lit.)

Description

Application

Reactant involved in:
• Copper-catalyzed arylation
• Palladium-catalyzed decarboxylative coupling
• Suzuki-Miyaura cross-coupling
• Oxidative carbocyclization / arylation
• Addition to arylpropargyl alcohols

Additionally used as a reactant for synthesizing biologically active molecules such as:
• Inhibitors of angiogenesis
• Biaryl-olefins with antiproliferative activities

Catalyzes ene carbocyclization of acetylenic dicarbonyl compounds

Packaging

1, 5 g in glass bottle

Other Notes

Contains varying amounts of anhydride

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
RTECS 
CY8980000
Protocols & Articles

Articles

Arylboronic Acids

We are pleased to present its complete selection of arylboronic acids, the building blocks of the Suzuki coupling experiment. Most arylboronic acids readily undergo dehydration reactions to give a cy...
ChemFiles 2001, 1.1, 5.
Keywords: Building blocks, Coupling reactions, Dehydration reaction, Suzuki coupling

Boronic Acids - ChemFiles 2007

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
ChemFiles 2007, 7.7, 3.
Keywords: Coupling reactions, Dehydration reaction, Suzuki coupling

Peer-Reviewed Papers
15

References

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