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327956 Sigma-Aldrich

(1R)-(+)-Nopinone

98%

Synonym: 6,6-Dimethylbicyclo[3.1.1]heptan-2-one

  • CAS Number 38651-65-9

  • Empirical Formula (Hill Notation) C9H14O

  • Molecular Weight 138.21

  •  MDL number MFCD08447116

  •  PubChem Substance ID 24859704

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Cell Biology, Chemical Synthesis, Chiral Building Blocks, Ketones,
Quality Level   100
assay   98%
optical activity   [α]20/D +16°, neat
refractive index   n20/D 1.479 (lit.)
bp   209 °C (lit.)
density   0.981 g/mL at 25 °C (lit.)
storage temp.   2-8°C
SMILES string   CC1(C)[C@H]2CCC(=O)[C@@H]1C2
InChI   1S/C9H14O/c1-9(2)6-3-4-8(10)7(9)5-6/h6-7H,3-5H2,1-2H3/t6-,7-/m0/s1
InChI key   XZFDKWMYCUEKSS-BQBZGAKWSA-N

Description

Application

(1R)-(+)-Nopinone may be used in the preparation of a chiral annulated indene derivative, which can be a potentially useful chiral ligand for transition metal complexes in asymmetric transformations. It may also react with secondary amines in cyclohexane to form the corresponding enamines.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Protocols & Articles
Peer-Reviewed Papers
15

References

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