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331074 Sigma-Aldrich

(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane

96%

Synonym: 2-[(4R)-2,2-Dimethyl-1,3-dioxolan-4-yl]ethanol

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Properties

Related Categories Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks More...
assay   96%
refractive index   n20/D 1.4390 (lit.)
bp   207 °C (lit.)
density   1.045 g/mL at 25 °C (lit.)
SMILES string   CC1(C)OC[C@@H](CCO)O1
InChI   1S/C7H14O3/c1-7(2)9-5-6(10-7)3-4-8/h6,8H,3-5H2,1-2H3/t6-/m1/s1
InChI key   YYEZYENJAMOWHW-ZCFIWIBFSA-N

Description

Application

(4R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane can be used:
• To introduce a chiral center selectively in the carbon chain C10 during the total synthesis of protectin D1.
• As a starting material in the total synthesis of an anti-diabetic molecule cytopiloyne.
• As a starting material in the preparation of 4-15N-amino-2-butane-1,2-diol, which is used to synthesize 15N-labeled oligodeoxynucleotides.

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
222.8 °F - closed cup
Flash Point(C) 
106 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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