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333670 Sigma-Aldrich

Tris(trimethylsilyl)phosphine

95%

Synonym: (P(TMS)3), Tris(trimethylsilyl)phosphane

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
assay   95%
refractive index   n20/D 1.502 (lit.)
bp   243-244 °C (lit.)
density   0.863 g/mL at 25 °C (lit.)
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
storage temp.   2-8°C
SMILES string   C[Si](C)(C)P([Si](C)(C)C)[Si](C)(C)C
InChI   1S/C9H27PSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3
InChI key   OUMZKMRZMVDEOF-UHFFFAOYSA-N

Description

Application

Tris(trimethylsilyl)phosphine (P(TMS)3) can be used as a precursor for the syntheses of:
• Indium phosphide (InP) and indium gallium phosphide (InGaP) nanocrystals, type III-V semiconductors.
• Chiral TMS-phospholane which can be further used to synthesize various bisphospholane ligands for asymmetric catalysis.

Packaging

1 g in ampule

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 2845 4.2
WGK Germany 
3
Protocols & Articles

Articles

III-V Material Sources

At the forefront of optoelectronic, lighting and data storage applications, III-V semiconductor materials continue to generate exciting new applications. III-V quantum dot heterostructures can addres...
Chemfiles Volume 4 Article 3
Keywords: Applications, Automotive, Electronics, Inductively coupled plasma, Mass spectrometry, Semiconductor

Solvothermal Synthesis of Nanoparticles

Solvothermal synthesis is a method for preparing a variety of materials such as metals, semiconductors, ceramics, and polymers. The process involves the use of a solvent under moderate to high pressu...
Prof. Bonnie Gersten
Chemfiles Volume 5 Article 13
Keywords: Absorption, Applications, Ceramics, Reductions, Semiconductor, Spectra, Type

Peer-Reviewed Papers
15

References

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