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335002 Sigma-Aldrich

Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

Synonym: Dihydridocarbonyltris(triphenylphosphine)ruthenium

  • CAS Number 25360-32-1

  • Linear Formula [(C6H5)3P]3Ru(CO)H2

  • Molecular Weight 919.79

  •  PubChem Substance ID 24860277

  •  NACRES NA.22

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Properties

Related Categories C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Ru Catalysts,
reaction suitability   core: ruthenium
  reagent type: catalyst
reaction type: C-H Activation
mp   161-163 °C (lit.)
storage temp.   room temp
SMILES string   [RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI   1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;;
InChI key   MLIYPCQSOXNTLJ-UHFFFAOYSA-N

Description

Application

• Catalyst for conversion of 1,4-alkynediols into pyrroles
• Catalyst for oxidation of primary alcohols to methyl esters
• Catalyst for rearrangement of oximes to amides
• Catalyst for C-C coupling via directed C-H activation
• Catalyst for enyne cyclization

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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