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335363 Sigma-Aldrich

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)

Synonym: (1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, Ni(dppp)Cl2

  • CAS Number 15629-92-2

  • Linear Formula [(C6H5)2P(CH2)3P(C6H5)2]NiCl2

  • Molecular Weight 542.04

  •  MDL number MFCD00015318

  •  PubChem Substance ID 24860309

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel Catalysts More...
InChI Key   ZBQUMMFUJLOTQC-UHFFFAOYSA-L
mp   213 °C (dec.) (lit.)
reaction suitability   reagent type: catalyst

Description

Application

Catalyst for:
• Synthesis of block-copolythiophenes
• Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
• Solid state metathesis polycondensation
• Polymerization of poly(3-alkoxythiophene)s
• Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
• Transfer condensation polymerization of conjugated polymers

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Catalysts and Metals

We supply a large variety of catalysts and metals that are of increasing importance to the synthetic organic chemist. This vast array of products is separated into two major categories: homogeneous a...
ChemFiles Volume 1 Article 3

Peer-Reviewed Papers
15

References

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