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336904 Sigma-Aldrich

Ethyldiphenylphosphine

98%

Synonym: Diphenylethylphosphine, NSC 151254

  • CAS Number 607-01-2

  • Linear Formula (C6H5)2PCH2CH3

  • Molecular Weight 214.24

  •  Beilstein/REAXYS Number 744253

  •  MDL number MFCD00015170

  •  PubChem Substance ID 24860439

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
assay   98%
refractive index   n20/D 1.614 (lit.)
bp   293 °C (lit.)
density   1.048 g/mL at 25 °C (lit.)
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string   CCP(c1ccccc1)c2ccccc2
InChI   1S/C14H15P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3
InChI key   WUOIAOOSKMHJOV-UHFFFAOYSA-N

Description

Application

Catalyst for:
• Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide
• Regio- and stereoselective hydroalkynylation of methylenecyclopropanes
• Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles
• Dimer to monomer conversion
• Tandem Morita-Baylis-Hillman/Michael addition reactions
• Platinum-catalyzed cyclization
• Regioselective and stereoselective [3+2] cycloaddition
• Platinum-catalyzed intermolecular hydroamination
• Hydroformylation reactions

Packaging

2 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 3334
WGK Germany 
3
RTECS 
SY9242500
Flash Point(F) 
230 °F
Flash Point(C) 
110 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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