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337498 Sigma-Aldrich

(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate

85%

Synonym: (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Crabtree’s catalyst, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex, [Ir(cod)(PCy3)(py)]PF6

  • CAS Number 64536-78-3

  • Empirical Formula (Hill Notation) C31H50F6IrNP2

  • Molecular Weight 804.89

  •  MDL number MFCD00075097

  •  PubChem Substance ID 24860483

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts More...
InChI Key   UJXHUUQZACSUOG-KJWGIZLLSA-N
assay   85%
mp   175 °C (dec.) (lit.)

Description

Packaging

50, 250 mg in glass bottle

Application

Catalyst for alkene hydrogenation, isomerization, and hydroboration; also for hydrogen isotope exchange reaction.

Homogeneous hydrogenation catalyst hydroboration catalyst.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

Robert Crabtree Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Robert Crabtree Group – Professor Product Portal
Keywords: Asymmetric synthesis, Hydrogenations

Peer-Reviewed Papers
15

References

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