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337528 Sigma-Aldrich

Allyl bromide

reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer

Synonym: 3-Bromo-1-propene

  • CAS Number 106-95-6

  • Linear Formula CH2=CHCH2Br

  • Molecular Weight 120.98

  •  Beilstein/REAXYS Number 605308

  •  EC Number 203-446-6

  •  MDL number MFCD00000244

  •  PubChem Substance ID 24860486

  •  NACRES NA.22

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Properties

Related Categories Chemical Synthesis, Other Protecting and Derivatizing Reagents, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents More...
grade   reagent grade
vapor density   4.2 (vs air)
InChI Key   BHELZAPQIKSEDF-UHFFFAOYSA-N
assay   97%
autoignition temp.   554 °F
contains   ≤1000 ppm propylene oxide as stabilizer
expl. lim.   7.3 %
refractive index   n20/D 1.469 (lit.)
bp   70-71 °C (lit.)
mp   −119 °C (lit.)
density   1.398 g/mL at 25 °C (lit.)
storage temp.   2-8°C

Description

Application

Allyl bromide can be used:
• For the synthesis of stereodefined allylated arenes via Suzuki-type coupling reaction.
• In Barbier-type allylation reactions of aldehydes and ketones.{17]
• To synthesize a monomer, 1-1-(allyloxy)-4-nitrobenzene while synthesizing nanostructured molecularly imprinted polymer for selective tryptophan assay in biological and pharmaceutical samples.

Packaging

1 L in glass bottle

250 mL in glass bottle

Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
RIDADR 
UN1099 - class 3 - PG 1 - Allyl bromide
WGK Germany 
3
RTECS 
UC7090000
Flash Point(F) 
30.2 °F
Flash Point(C) 
-1 °C

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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