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337773 Sigma-Aldrich

Chlorodiisopropylphosphine

96%

  • CAS Number 40244-90-4

  • Linear Formula [(CH3)2CH]2PCl

  • Molecular Weight 152.60

  •  MDL number MFCD00015027

  •  PubChem Substance ID 24860498

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
InChI Key   JZPDBTOWHLZQFC-UHFFFAOYSA-N
assay   96%
refractive index   n20/D 1.475 (lit.)
bp   69 °C/33 mmHg (lit.)
density   0.959 g/mL at 25 °C (lit.)
functional group   phosphine
reaction suitability   reagent type: ligand
reaction type: Arylations

Description

Application

Chlorodiisopropylphosphine can be used:
• To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
• As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
• A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2924 8(3) / PGII
WGK Germany 
3
Flash Point(F) 
39.2 °F
Flash Point(C) 
4 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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