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340367 Sigma-Aldrich

(1R)-(−)-Nopol

98%

Synonym: (−)-Nopol, (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol, 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol

  • CAS Number 35836-73-8

  • Empirical Formula (Hill Notation) C11H18O

  • Molecular Weight 166.26

  •  Beilstein/REAXYS Number 3196379

  •  EC Number 252-744-2

  •  MDL number MFCD00075187

  •  PubChem Substance ID 24860803

  •  NACRES NA.22

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Properties

Related Categories Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks More...
assay   98%
optical activity   [α]24/D −37°, neat
refractive index   n20/D 1.493 (lit.)
bp   230-240 °C (lit.)
density   0.973 g/mL at 25 °C (lit.)
SMILES string   CC1(C)[C@H]2CC=C(CCO)[C@@H]1C2
InChI   1S/C11H18O/c1-11(2)9-4-3-8(5-6-12)10(11)7-9/h3,9-10,12H,4-7H2,1-2H3/t9-,10-/m0/s1
InChI key   ROKSAUSPJGWCSM-UWVGGRQHSA-N

Description

General description

(1R)-(-)-Nopol is a chiral terpenol derivative.

Application

(1R)-(-)-Nopol may be used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids by reacting with tetraphosphorus decasulfide and 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides, respectively. It may also react with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization.

Packaging

100 mL in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
208.4 °F - closed cup
Flash Point(C) 
98 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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