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341045 Sigma-Aldrich

2-Ethyl-2-methyl-1,3-dioxolane

99%

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Properties

Related Categories Acetals, Ketals & Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds More...
assay   99%
refractive index   n20/D 1.409 (lit.)
bp   116-117 °C (lit.)
density   0.929 g/mL at 25 °C (lit.)
storage temp.   room temp
SMILES string   CCC1(C)OCCO1
InChI   1S/C6H12O2/c1-3-6(2)7-4-5-8-6/h3-5H2,1-2H3
InChI key   UPZFLZYXYGBAPL-UHFFFAOYSA-N

Description

Application

2-Ethyl-2-methyl-1,3-dioxolane was employed as reagent in the selective ketalization of 1-oxo functions of 8a-methyl 1,6-dioxo 1,2,3,4,6,7,8,8a-octahydronaphthalene and 7a-methyl 1,5-dioxo 5,6,7,7a-tetrahydroindane. It was also employed in the enantioselective total synthesis of (-)-strychnine.

Packaging

50, 250 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Target organs 
Respiratory system
RIDADR 
UN 1993BF 3 / PGII
WGK Germany 
WGK 3
RTECS 
JH7700000
Flash Point(F) 
55.4 °F - closed cup
Flash Point(C) 
13 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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