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343706 Sigma-Aldrich

Dichloro(p-cymene)ruthenium(II) dimer

Green Alternative

Synonym: (p-Cymene)ruthenium(II) chloride dimer, Benzene, 1-methyl-4-(1-methylethyl)-, ruthenium complex

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Properties

Related Categories 12 Principles Aligned Products, C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis,
reaction suitability   reagent type: catalyst
reaction type: C-H Activation
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   247.0-250.0 °C (dec.) (lit.)
SMILES string   Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2
InChI   1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key   LAXRNWSASWOFOT-UHFFFAOYSA-J

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Hydrosilylation Catalysts

Catalyst for greener amine synthesis by reduction of imines with PMHS or hydrogen-borrowing.

A Practical and Benign Synthesis of Primary Amines through Ruthenium-Catalyzed Reduction of Nitriles

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 2
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Encapsulated Os Catalysts

Sigma-Aldrich, in collaboration with Reaxa Ltd., is pleased to offer first-to-market catalysts for use in practical synthetic transformations. Reaxa has immobilized osmium tetroxide, a toxic and vola...
Aldrich ChemFiles 2006, 6.5, 6.
Keywords: Dihydroxylations, Immobilization

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Hydrosilylation Catalyst in Chemical Synthesis

Vinylsilanes are versatile organometallic reagents that participate in a variety of reaction paradigms such as Tamao–Fleming oxidation, olefin metathesis, Pd-catalyzed cross-coupling, protodesilylati...
Keywords: Aldol condensation, Asymmetric synthesis, Catalysis, Condensations, Cross couplings, Cyclizations, Cycloadditions, Hydrosilylations, Metathesis, Methods, Olefin metathesis, Oxidations, Reductions, Solvents

Peer-Reviewed Papers
15

References

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