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  • 344087 - (−)-(R)-N,N-Dimethyl-1-[(S)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine

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344087 Sigma-Aldrich

(−)-(R)-N,N-Dimethyl-1-[(S)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine

95%

Synonym: [R,R]-1-[1-Dimethylaminoethyl]-1′,2-bis[diphenylphosphino]ferrocene

  • CAS Number 74311-56-1

  • Empirical Formula (Hill Notation) C38H37FeNP2

  • Molecular Weight 625.50

  •  MDL number MFCD00075284

  •  PubChem Substance ID 24861223

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
assay   95%
optical activity   [α]20/D −350°, c = 0.5 in chloroform
mp   143-144 °C (lit.)
storage temp.   room temp
SMILES string   [Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.C[C@H]([C]4[CH][CH][CH][C]4P(c5ccccc5)c6ccccc6)N(C)C
InChI   1S/C21H23NP.C17H14P.Fe/c1-17(22(2)3)20-15-10-16-21(20)23(18-11-6-4-7-12-18)19-13-8-5-9-14-19;1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h4-17H,1-3H3;1-14H;/t17-;;/m1../s1
InChI key   VUJPTJYMSBMZOZ-ZEECNFPPSA-N

Description

Application

Ligand used in the enantioselective silylation of allylic chlorides.

Packaging

100 mg in clear glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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