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344125 Aldrich

(R)-(+)-N,N-Dimethyl-1-ferrocenylethylamine

97%

Synonym: (R)-Ugi′s amine, (R)-(+)-[1-(Dimethylamino)ethyl]ferrocene

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
InChI Key   ISOLNZQTVMCEOI-YCBDHFTFSA-N
assay   97%
optical activity   [α]20/D +13°, c = 1 in ethanol (5 h)
refractive index   n20/D 1.589(lit.)
bp   120-121 °C/0.7 mmHg(lit.)
density   1.222 g/mL at 20 °C(lit.)

Description

Packaging

500 mg in ampule

Application

(R)-(+)-N,N-Dimethyl-1-ferrocenylethylamine may be used as a starting material to synthesize:
• chiral 1,2-disubstituted ferrocenyl amino alcohols
• ferrocene-based P-chiral phosphine ligands
• optically active α-ferrocenyl tertiary amines

Ligand used in the preparation of chiral allylic alcohols, axially chiral allenecarboxylic esters, and rhodium(I)-catalyzed asymmetric hydrosilylation of ketones.

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
235.4 °F
Flash Point(C) 
113 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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Description

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94791 SnapIT Ampule Opener, Regular, for 1-2ml, 5-10ml, 10-15ml ampoules
43917 SnapIT Ampule Opener, large, for 5-10ml, 10-15ml, 20-25ml ampoules

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